Each episode of this series include multiple segments: The first and last were "Laff-A-Lympics" segments, the other ones were "Captain Caveman and the Teen Angels", "Scooby-Doo" and "Dynomutt" segments. The "Laff-A-Lympics" segments feature 45 Hanna-Barbera cartoon characters (classic and otherwise) competing for gold medals in wacky events. Events include racing on ostriches, camels, kangaroos, rickshaws and unicycles, as well as scavenging for creatures like the Abominable Snowman, vampires, and the Loch Ness Monster.
Episode 1
Teams compete in downhill skiing, ice skating, tobagganing.
Episode 2
While on a road trip, Captain Caveman and the Teen Angels are given a mysterious key by a stranger.
Episode 3
A museum curator and two geology students impersonate Viking ghosts to keep people away from a lake and steal the area's thermal energy.
Episode 4
The evil Beastwoman uses her multifrequency Beastwhistle to call all the animals in the Big city Zoo to break out of their cages and drive the people out. Dog Wonder finds Beastwoman in a dog parlor where he gets a poodle chip. D.W. succumbs to the Beastwhistle and, following Beastwoman's commands, captures The Blue Falcon and puts him in a maneating plant. Beastwoman orders her subjects to spread her fast growing seeds across Big City, which she plans to convert into a giant jungle!
Episode 5
Teams compete in sumo wrestling, tennis, and batting.
Episode 6
Teams compete in cliff diving, underwater relays, speed boat racing.
Episode 7
While at the beach with some friends, Captain Caveman and the Teen Angels see a ship mysteriously vanish.
Episode 8
The gang visits a friend on a forbidding island reputed to be the home of vampires.
Episode 9
B.F. manages to release himself and reprogram Dog Wonder so he won't obey Beastwoman's Beastwhistle. B.W., meanwhile, employs some bird to seed the clouds and have them rain on the seeded Big City, turning it into a jungle. The Daring Duo learn she plans to do this to the rest of the U.S.A. via rocket power, so Blue Falcon detains Beastwoman whilst Dynomutt goes up with the rocket which crashes into the lake and D.W. becomes a moss-covered mechanical mutt. Blue Falcon severs Beastwoman's powers by snipping her veins, and Big City is restored to normal. Blue Falcon attempts to shear Dynomutt's veins, but the latter decides to shake them off by dancing the Hula.
Episode 10
Teams compete in climbing Big Ben, fox hunting, and skateboard polo.
Episode 11
Teams compete in swamp buggy racing, waterskiing, track raceing.
Episode 12
At the airport, some jewels are stolen by a mysterious figure.
Episode 13
During a hang-gliding competition, the gang investigates ghostly dinosaurs and cave-men in a Western canyon.
Episode 14
Petty thug Norbert Prindle, alias The Glob, eludes Dynomutt and Blue Falcon at The Crowne Art Gallery and makes off with the multimillion dollar Baltese Falcon, a 2"" statue of solid diamonds. The Dyno-Computer Tracker traces The Glob and the heroes almost collide with the thief. The Glob escapes into a manhole where Dynomutt gets the Baltese Falcon back from him and hides it in a curio shop amongst 9 other phoney Baltese Falcons. The Daring Duo corners Norbert Prindle and his mob at their hideout, but Prindle eludes them again, washing the heroes down the channel by a flood of water. They return to the curio shop to retrieve the Baltese Falcon, only to find that it and the other phoney Baltese Falcons have been sold.
Episode 15
Teams compete in rickshaw racing, ping pong, and gymnastics.
Episode 16
Teams compete in dune buggy racing, Fill Up The Oasis race.
Episode 17
On a charter boat, Captain Caveman and the Teen Angels are chatting with a friend whose father is being honored for his role in a play when suddenly the lights go out and a necklace is stolen.
Episode 18
The filming of Scooby-Dee's new film is disrupted when a phantom appears on the set.
Episode 19
As Dynomutt escapes, Blue Falcon becomes Blue Blob. Dog Wonder races his blue buddy to The Falcon's Lair, where he sculpts him back to normal and spritzes him with The Falcon Instant Hardening Spray, and corner The Glob and his minions just as they nab the true Baltese Falcon. They capture Norbert Prindle in a huge goblet, and turn the crooks in and return the Falcon to the Crowne Art Gallery. Later, in the Falcon's Lair, D.W. tries to sculpt a ""Bluetese Falcon"", using B.F. for a model, but his creation shatters to pieces before he gets to profit big from it.
Episode 20
Teams compete in Lochness Photograph race, and three-legged kilt racing.
Episode 21
Teams compete in the Tour De France, Eiffel Tower climbing.
Episode 22
At the circus, tigers are disappearing. Captain Caveman and the Teen Angels investigate and discover a phantom has been haunting the circus.
Episode 23
Shag and Scooby play decoy to uncover the truth behind a phantom racer and some disappearing racecars.
Episode 24
The Daring Duo are on the trail of Madame Ape Face who has swiped the face of Sophia Florenzi and plans tosteal all of the beautiful faces of the starlets of Big City. They catch up with The Madame at GaGa Galore's costume party but her face is stolen. Chasing Ape Face , Blue Falcon and Dog Wonder find themselves headed down a conveyor belt into a cold cream machine!
Episode 25
Teams compete in boomerang throwing, and kangaroo racing.
Episode 26
Teams compete in pole vaulting, discus.
Episode 27
The Central City Kings have disappeared due to a panther.
Episode 28
The gang spends a stormy night at Hatfield's cabin, only to see a witch transform their host into a frog. Searching for a solution, they encounter a zombie and a witch's cave.
Episode 29
Saved by The Falcon Fan Snapper, The Daring Duo rush to the aid of the most probable victims. When Fifi Foray wins a beauty contest, Dog Wonder disguises himself as Fifi, and an ensuing scuffle with Madame Ape Face results in D.W.'s face stolen. (Dynoape, Ape Wonder?! It'll never be the same!) Using The Dyno-Radar Hand Detector, the heroes find The Madame's lair and Dog Wonder's face is restored. They catch Ape Face in the act of pilfering Sarah Showerfaucet's face at her apartment. Blue Falcon captures The Madame just as she tosses Sarah's face out the window, but Dog Wonder manages to catch it before it shatters on the concrete below.
Episode 30
Teams compete in pole vaulting, discus, rail cart racing, and keelboat racing.
Episode 31
Teams compete in motor scooter racing, canal boat racing.
Episode 32
The television station, KXXX, is taken off the air when a criminal cuts the antenna.
Episode 33
The gang wins a South Seas cruise and stumbles upon a mystery involving a time machine and a futuristic monster.
Episode 34
Lurking in Big City is The Shadowman, who mysteriously knows all of the plans of The Crime Commission. The Daring Duo are called in when the 700-karat Shmope Diamond is swiped. As they respoind, they spot a shadow sneaking off with plates for new $20 bills stolen from an armored car. The Shadowman later manages to kill two birds with one stone by making off with a secret gold shipment and framing Mayor Gaunt (who is captured in The Dyno Bad Guy Box) all in one shot.
Episode 35
Teams compete in hang gliding, skydiving, and hot-air balloon racing.
Episode 36
Teams compete in Touch the Tip of the Pyramid race, camel racing.
Episode 37
A villain named Claw uses an aging gun to turn a rock star into an old man.
Episode 38
A huge sea monster disrupts the kids' beach party, but when they take refuge in an old house they run into a ghostly sea captain whose spirit has been stolen by the monster.
Episode 39
No overview available.
Episode 40
Teams compete in knight racing, and a rescue contest.
Episode 41
Teams compete in bullfighting, gypsy wagon race.
Episode 42
When a mummy comes to life and kidnaps an archeologist, Captain Caveman and the Teen Angels investigate.
Episode 43
Teams compete in hang the bell on the Abominable Snowman, relay racing to the top of Everest.
Episode 44
Exotic locales in India's lush Bengal Jungle provide the backdrops for today's exciting events.
Episode 45
With their friend, a prince of a small country, Captain Caveman and the Teen Angels go skiing. When the scepter is stolen by a Snowwolfman, they investigate.
Episode 46
Exotic locales in Israel's Negev Desert provide the backdrops for today's exciting events.
Episode 47
Teams compete in jungle boat racing, vine swinging.
Episode 48
In India, when a Royal White Elephant is stolen by an evil sorcerer, Captain Caveman and the Teen Angels investigate.
Episode 49
Teams compete in rollerskating, and fishing.
Episode 50
Teams compete in mule racing, tightrope racing.
Episode 51
Captain Caveman and the Teen Angels are assisting Dee Dee's uncle, Frank Skyes, with a fur delivery. When the furs disappear, it is up to them to find out what happened.
Episode 52
Teams compete in Catch the Leprechaun, and hole-in-one golf contest.
Episode 53
The teams' wild events occur in the climate of tropical Hawaii.
Episode 54
In Wyoming, rumors of a horse that is possessed by a demon are rampant. And they seem to be true. Captain Caveman and the Teen Angels have arrived to investigate. Just as they are investigating, a bank robbery occurs.
Episode 55
The teams' wild events occur in the climate of icy Norway.
Episode 56
The teams' crazy contests occur in the climate of the frigid North Pole!
Episode 57
Captain Caveman and the Teen Angels go to a research facility after they spot an alien spacecraft landing there. They discover that an alien robot supposedly stole a top secret energy source.
Episode 58
The teams' crazy contests occur in the climate of tropical Tahiti.
Episode 59
The scenic locales for today's crazy contests is the rustic Rustler's Gulch, Arizona.
Episode 60
Captain Caveman and the Teen Angels got to Farthington Mansion with Taffy's Aunt Gladys to see a magic show. When some jewels are stolen, Captain Caveman and the Teen Angels investigate.
Episode 61
The scenic locales for today's crazy contests is the picturesque Holland.
Episode 62
Today's wacky contests include tree cutting in Canada.
Episode 63
In Oregon, when the star athlete of a sports team is kidnapped, Captain Caveman and the Teen Angels investigate. Very soon, they have found Juice Brenner. Or have they? He is acting strangely.
Episode 64
Today's wacky contests include a flying carpet race in Baghdad!